Well, after a few months of investigating, over many many tanks of fuel, I would like to share my findings with you all as it may even be of help to some, if not interesting to the rest of you
Not firstly, I do around 600 motorway miles per week in my 2002 Mini Cooper (Chilli), so I have had the chance to go through many tanks of petrol! I have unfortunately not got the OBC so havent been able to easily record MPG readings. I must take the time to work mine out! However, the purpose of my investigation wasnt really to find the exact MPG figures, it wa sjust to find out which fuel seems to suit my Cooper better
Now when I first started using super unleaded I went for the
BP Ultimate 97 Octane. Now stepping up to this I noticed a definite improvement on economy (after a a few tanks of it). I was getting round 50 miles out of it with motorway driving. When it came to driving around town I didnt really see much improvement.
After the Tesco Fuel crisis had died down I decided to give the
Tesco Super Unleaded a go. Now unfortunately I cant find a store anywhere locally, or along my route to work that sells the Super Unleaded 99, so I had to go with the 97. This being the case I didnt think it would be any different to the BP 97, however again, with motorway driving I saw a definite improvement over the BP! Granted, not by much, probably an extra 10 miles or so out of a tank but the Tesco fuel is also cheaper, so I was impressed

Less money and even more miles!
Before stepping up to a 99 octane fuel I gave the Esso Super unleaded a try and found it to be just as good as the BP Ultimate.
So... next came the Grand Daddy.. I started to run with
Shell V-Power. Now the first time I filled up with V-Power I used up the tank with mostly town driving but a little extra urban. I didnt really see any improvement over the cheaper 97 octane fuels, but I am wondering if I needed a couple of tanks for the ECU to adjust? So.. despite being dissapointed with the first tank I filled up again for the Lakes and Mountains Run in Wales. Now this time, I was impressed

I spent most of the run in 3rd and 4th gear (Damn you S's as the front

). High revs, hard braking and generally what I would class as fuel hungry driving. This didnt make a difference though! I was able to acheive the same number of miles out of my full tank, as I was during motorway driving with the cheaper fuels

Great!
BUT (yes there is always a but!...)... following my great experience with V-Power I carried on using it, despite the high price! Not since then I have only used V-Power and have again found that with Urban driving then it is incredibly efficient! The problem came during the week with my commuting journeys to and from work. The V-power - wierdly - doesnt give as good economy on the motorway, as the cheaper fuels do

With this one I am confused. A few more tests with Urban driving and again the V-Power delivers, so why not when driven extra urban?
I have recently switched back to Tesco 97, Im on my second tank for my commutes to and from work and my economy has improved as I expected, over the V Power.
Just to confirm, I tried to make sure I drove in the same style during this whole investigation and keep all constraints at a constant. Obviously there will be slight differences as somedays there is more traffic than other days. However I think I have gone through enough full tanks to be able to make the judgements I have.
Conclusions BP Ultimate 97 - Good Improvement all round over Unleaded 95
Tesco Super Unleaded 97 - Good Improvement all round over Unleaded 95, slightly more efficient than BP Ultimate 97
Esso Super Unleaded - Good Improvement all round over Unleaded 95
Shell V-Power - Incredible economy for Urban driving. Not so good for Extra Urban
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I hope this has been of interest or even help to some. I would greately appreciate feedback, questions, and personal experiences

And can anyone help me out with V-Power issues?
Kind Regards
Dan