Sounds like it needs to be bled again.
Sorry to hi Jack this thread but I have a 2005 mini where the coolant will escape from the top of the thermostat housing cap, I replaced the entire thermostat and housing but the problem stayed, is this what happened to your Ollie? I have heard that unless you use the bwm thermostat housing you can have all sorts of problems, I did get it from euro car parts so assumed it would be OK? Where did you get the cap from?If your still having issues replace the pressure cap, one on mine looked fine but letting the engine sit and get up to 100 degrees it would boil over before getting to the radiator fan switch on temperature of 105 degrees, only about £15 for a new cap nice easy fix!
OK mine hasn't done that but i guess if both seals aren't doing there job I mine wouldn't fill the water bottle but just come straight out the side, think I have found the part on ebay might order it, was just about to send it to the garage I have done a compression test and the head is good so I was starting to be at a loss for ideasNo I replaced the cap circled in red, it wasn’t leaking out the top of it just past the seal inside causing the expansion tank to fill
Had the pipe off and it wasn't blocked, if both seals have failed I am assuming it takes the path of least resistance the housing gasket and stat itself was only £25 and I imagine £13 of that isn't spent on the cap alone, so might just buy the cap on ebay and give that a goInteresting that you get nothing building up in the expansion tank? Possibly a blocked line to the expansion tank? Should be an easy check, otherwise I’m not sure how it would leak past both seals on the cap without filling the tank